I have never heard of anyone pouring Coke into an engine before now, but I suppose there is a first time for everything. Coke contains phosphoric acid, which is a common ingredient in commercial rust removal products, so that could be the reason it worked for you.
That said, it can't possibly be good for the engine to leave the Coke in there for any length of time. I would strongly recommend disassembling the engine as soon as possible and cleaning the parts.
Ray
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